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A Supramolecular Tetradecanuclear Copper( II ) Polyoxotungstate
Author(s) -
Mialane Pierre,
Dolbecq Anne,
Marrot Jérôme,
Rivière Eric,
Sécheresse Francis
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200351486
Subject(s) - divalent , copper , supramolecular chemistry , chemistry , halide , crystallography , metal , supramolecular assembly , divalent metal , cluster (spacecraft) , stereochemistry , inorganic chemistry , crystal structure , organic chemistry , programming language , computer science
Four {SiW 9 O 34 } units enclose a 14 Cu II cluster obtained through halide supramolecular assembly, leading to the polyanion containing the highest number of divalent metal cations (see picture; W blue, Si yellow, Br orange, Cu green, O red).