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Palladium‐Catalyzed Electrophilic Substitution via Monoallylpalladium Intermediates
Author(s) -
Solin Niclas,
Kjellgren Johan,
Szabó Kálmán J.
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200351477
Subject(s) - palladium , electrophile , moiety , chemistry , catalysis , reactivity (psychology) , nucleophile , pincer movement , electrophilic substitution , substitution reaction , nucleophilic substitution , medicinal chemistry , organic chemistry , medicine , alternative medicine , pathology
Nucleophilic rather than electrophilic reactivity is ascribed to the allyl moiety in (η 1 ‐allyl)palladium complexes such as 1 , which are generated catalytically from allylstannanes and a palladium pincer complex and react smoothly with aldehydes.