Helical, Chiral Polyisocyanides Bearing Ferrocenyl Groups as Pendants: Synthesis and Properties | Zendy

Hida Noriyuki | Zendy; Takei Fumie | Zendy; Onitsuka Kiyotaka | Zendy; Shiga Keiichiro | Zendy; Asaoka Sadayuki | Zendy; Iyoda Tomokazu | Zendy; Takahashi Shigetoshi | Zendy

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Helical, Chiral Polyisocyanides Bearing Ferrocenyl Groups as Pendants: Synthesis and Properties

Author(s) -

Hida Noriyuki,

Takei Fumie,

Onitsuka Kiyotaka,

Shiga Keiichiro,

Asaoka Sadayuki,

Iyoda Tomokazu,

Takahashi Shigetoshi

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351456

Subject(s) - polymerization , chemistry , polymer , polymer chemistry , ferrocene , optically active , crystallography , circular dichroism , stereochemistry , electrochemistry , organic chemistry , electrode

Winding up helices : The title compounds are prepared by a living polymerization of optically active ferrocenyl isocyanides initiated with a dinuclear Pt–Pd complex. Electrolytic CD and UV spectra suggest that the polymers exhibit reversible conformational change in response to oxidation and reduction of the ferrocenyl pendants (see scheme).

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