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Terpenoid‐Derived Sulfides as Ultimate Organic Sulfur Compounds in Extensively Desulfurized Fuels
Author(s) -
CharriéDuhaut Armelle,
Schaeffer Christine,
Adam Pierre,
Manuelli Pascal,
Scherrer Pierre,
Albrecht Pierre
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200351426
Subject(s) - organosulfur compounds , hydrodesulfurization , sulfur , chemistry , organic chemistry , mass spectrometry , environmental chemistry , chromatography
Extremely hydrodesulfurization‐resistant organosulfur compounds of biological origin are present in trace amounts in highly desulfurized fuels. A series of these compounds (see picture; left) was characterized by mass spectrometry and NMR spectroscopic structural elucidation of the corresponding sulfones (right), which were isolated after selective oxidation.