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Alkynylboronic Esters as Efficient Dienophiles in Cobalt‐Catalyzed Diels–Alder Reactions
Author(s) -
Hilt Gerhard,
Smolko Konstantin I.
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200351404
Subject(s) - cobalt , diels–alder reaction , catalysis , chemistry , substructure , boron , organic chemistry , combinatorial chemistry , structural engineering , engineering
Versatile building blocks with a dihydroaromatic vinylic boron substructure can be generated efficiently by cobalt‐catalyzed Diels–Alder reactions and used in Suzuki coupling reactions for the synthesis of functionalized polycyclic compounds (see scheme).