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Dibenzophosphasemibullvalene
Author(s) -
Geier Jens,
Frison Gilles,
Grützmacher Hansjörg
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200351388
Subject(s) - blame , thermal decomposition , scheme (mathematics) , ligand (biochemistry) , decomposition , content (measure theory) , strain (injury) , chemistry , phosphorus , computer science , mathematics , organic chemistry , psychology , biology , social psychology , mathematical analysis , biochemistry , receptor , anatomy
Strain is not to blame : Controlled thermolysis of 1 afforded dibenzo‐1‐phosphasemibullvalene 2 (see scheme). This unstable compound can be stabilized as a ligand in the complex [W(CO) 5 ( 2 )]. Although the sum of bond angles at phosphorus (220°) is very small, 2 is only a little strained.
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