A Near‐Infrared Electrochromic Window Based on an Sb‐Doped SnO 2  Electrode Modified with a Ru–Dioxolene Complex | Zendy

GarcíaCañadas Jorge | Zendy; Meacham Andrew P. | Zendy; Peter Laurence M. | Zendy; Ward Michael D. | Zendy

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A Near‐Infrared Electrochromic Window Based on an Sb‐Doped SnO 2 Electrode Modified with a Ru–Dioxolene Complex

Author(s) -

GarcíaCañadas Jorge,

Meacham Andrew P.,

Peter Laurence M.,

Ward Michael D.

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351338

Subject(s) - electrochromism , window (computing) , substrate (aquarium) , nanocrystalline material , materials science , electrode , doping , redox , optoelectronics , infrared , nanotechnology , chemistry , optics , computer science , metallurgy , oceanography , physics , geology , operating system

A window of opportunity : The ligand‐centred redox activity of complex 1 (depicted) is exploited to make an electrochromic window, which demonstrates rapid and reversible changes in optical transmission at 940 nm. The window is made by adsorbing 1 onto a nanocrystalline Sb‐doped SnO 2 film attached to a transparent conducting substrate and cycling the applied potential through the catecholate/semiquinone redox couple.

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