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A Tris(carbene) Pincer Complex: Monomeric Platinum Carbonyl with Three Bound Carbene Centers
Author(s) -
Lin Guanyang,
Jones Nathan D.,
Gossage Robert A.,
McDonald Robert,
Cavell Ronald G.
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200351320
Subject(s) - carbene , platinum , chemistry , carbon monoxide , monomer , pincer movement , medicinal chemistry , silylation , imine , tris , photochemistry , polymer chemistry , organic chemistry , catalysis , polymer , biochemistry
Carbon monoxide replaces cod in the mono carbene phosphane imine complex 1 (see picture) to form, through a double silyl migration reaction, the remarkable complex 2 containing three carbene centers bound to platinum (cod=cycloocta‐1,5‐diene).
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