A Phosphorane as Supported Acylanion Equivalent: Linker Reagents for Smooth and Versatile CC Coupling Reactions | Zendy

Weik Steffen | Zendy; Rademann Jörg | Zendy

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A Phosphorane as Supported Acylanion Equivalent: Linker Reagents for Smooth and Versatile CC Coupling Reactions

Author(s) -

Weik Steffen,

Rademann Jörg

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351190

Subject(s) - phosphorane , linker , nucleophile , reagent , chemistry , cleavage (geology) , combinatorial chemistry , stereochemistry , sequence (biology) , computational chemistry , computer science , organic chemistry , catalysis , materials science , programming language , biochemistry , fracture (geology) , composite material

Smoothly linked : Polymer‐supported phosphorane 1 is a C‐nucleophile that can be acylated under mild reaction conditions. Diversely substituted α‐ketocarbonyl and α‐hydroxycarbonyl compounds 2 are furnished following to a reaction sequence including oxidative cleavage of the supported phosphoranes.

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