Solid‐State Supramolecular Organization of Supermolecules into a Truly Molecular Zeolite | Zendy

Shiu KomBei | Zendy; Lee HongChan | Zendy; Lee GeneHsiang | Zendy; Ko BaoTsan | Zendy; Wang Yu | Zendy; Lin ChuChieh | Zendy

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Solid‐State Supramolecular Organization of Supermolecules into a Truly Molecular Zeolite

Author(s) -

Shiu KomBei,

Lee HongChan,

Lee GeneHsiang,

Ko BaoTsan,

Wang Yu,

Lin ChuChieh

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351149

Subject(s) - microporous material , supramolecular chemistry , hexagonal crystal system , zeolite , solid state , state (computer science) , diffusion , crystallography , materials science , polymer science , chemistry , thermodynamics , physics , computer science , organic chemistry , composite material , catalysis , crystal structure , algorithm

Letting out the guests : The hexagonal closest packing of discrete triangular‐tube‐shaped organometallic supermolecules of eclipsed‐[{Ru 2 (CO) 4 (PPh 3 ) 2 }(μ‐4,4′‐O 2 CC 6 H 4 C 6 H 4 CO 2 )] 3 in the solid state (see picture) permits the production of a microporous material that is not only thermally stable up to 181 °C, but also allows diffusion at room temperature of molecular guests without the framework collapsing.

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