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Solid‐State Supramolecular Organization of Supermolecules into a Truly Molecular Zeolite
Author(s) -
Shiu KomBei,
Lee HongChan,
Lee GeneHsiang,
Ko BaoTsan,
Wang Yu,
Lin ChuChieh
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200351149
Subject(s) - microporous material , supramolecular chemistry , hexagonal crystal system , zeolite , solid state , state (computer science) , diffusion , crystallography , materials science , polymer science , chemistry , thermodynamics , physics , computer science , organic chemistry , composite material , catalysis , crystal structure , algorithm
Letting out the guests : The hexagonal closest packing of discrete triangular‐tube‐shaped organometallic supermolecules of eclipsed‐[{Ru 2 (CO) 4 (PPh 3 ) 2 }(μ‐4,4′‐O 2 CC 6 H 4 C 6 H 4 CO 2 )] 3 in the solid state (see picture) permits the production of a microporous material that is not only thermally stable up to 181 °C, but also allows diffusion at room temperature of molecular guests without the framework collapsing.