Hexanuclear Manganese( III ) Single‐Molecule Magnets | Zendy

Milios Constantinos J. | Zendy; Raptopoulou Catherine P. | Zendy; Terzis Aris | Zendy; Lloret Francesc | Zendy; Vicente Ramon | Zendy; Perlepes Spyros P. | Zendy; Escuer Albert | Zendy

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Hexanuclear Manganese( III ) Single‐Molecule Magnets

Author(s) -

Milios Constantinos J.,

Raptopoulou Catherine P.,

Terzis Aris,

Lloret Francesc,

Vicente Ramon,

Perlepes Spyros P.,

Escuer Albert

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351079

Subject(s) - manganese , magnet , metal , molecule , oxidation state , chemistry , crystallography , single molecule magnet , molecular magnets , nanotechnology , materials science , physics , organic chemistry , magnetic field , magnetization , quantum mechanics

Clusters of magnets : The first examples of manganese single‐molecule magnets (SMMs) consisting exclusively of trivalent metal centers are reported. These are hexanuclear clusters containing the [Mn III 6 (μ 3 ‐O) 2 (μ 2 ‐OR) 2 ] 12+ core (see picture, Mn yellow, O red) and have an S =4 ground state. Variation of the oxygen‐containing ligands allows a potentially large family of SMMs to be prepared.

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