Generation, Trapping, and Dimerization of Pentacyclo[6.4.0.0 2,10 .0 3,7 .0 4,9 ]dodeca‐5,8,11‐triene: An Uncatalyzed Thermal [2+2+2+2] Cycloaddition | Zendy

Camps Pelayo | Zendy; Fernández José A. | Zendy; Vázquez Santiago | Zendy; FontBardia Mercè | Zendy; Solans Xavier | Zendy

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Generation, Trapping, and Dimerization of Pentacyclo[6.4.0.0 2,10 .0 3,7 .0 4,9 ]dodeca‐5,8,11‐triene: An Uncatalyzed Thermal [2+2+2+2] Cycloaddition

Author(s) -

Camps Pelayo,

Fernández José A.,

Vázquez Santiago,

FontBardia Mercè,

Solans Xavier

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351070

Subject(s) - trapping , alkene , cycloaddition , derivative (finance) , scheme (mathematics) , chemistry , organic chemistry , catalysis , mathematics , ecology , financial economics , economics , biology , mathematical analysis

Simultaneous formation of four CC bonds and three rings occurs in the unique uncatalyzed thermal [2+2+2+2] cycloaddition to give the tridecacyclotetracosane derivative 2 , which takes place when the highly pyramidalized alkene 1 is generated in the absence of a trapping agent (see scheme).

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