Quantitative Formation of Sandwich‐Shaped Trinuclear Silver( I ) Complexes and Dynamic Nature of Their  P ⇌ M  Flip Motion in Solution | Zendy

Hiraoka Shuichi | Zendy; Harano Koji | Zendy; Tanaka Takaaki | Zendy; Shiro Motoo | Zendy; Shionoya Mitsuhiko | Zendy

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Quantitative Formation of Sandwich‐Shaped Trinuclear Silver( I ) Complexes and Dynamic Nature of Their P ⇌ M Flip Motion in Solution

Author(s) -

Hiraoka Shuichi,

Harano Koji,

Tanaka Takaaki,

Shiro Motoo,

Shionoya Mitsuhiko

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351068

Subject(s) - motion (physics) , twist , ion , scheme (mathematics) , rotation (mathematics) , chemistry , flip , content (measure theory) , crystallography , physics , stereochemistry , computer science , biochemistry , mathematical analysis , classical mechanics , mathematics , organic chemistry , geometry , artificial intelligence , apoptosis

Molecular flippers: The Ag 3 L 2 complexes, which are quantitatively formed from two disk‐shaped tridentate ligands (thiazolyl‐ or pyridyl‐based) and three Ag + ions, are helical and twist between the P and M forms (see scheme). The flip motion includes a relative 120° rotation between the two disk‐shaped ligands connected by the Ag + ions.

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