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IBX Amides: A New Family of Hypervalent Iodine Reagents
Author(s) -
Zhdankin Viktor V.,
Koposov Alexey Y.,
Netzel Brian C.,
Yashin Nikolai V.,
Rempel Brian P.,
Ferguson Michael J.,
Tykwinski Rik R.
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200351018
Subject(s) - hypervalent molecule , iodine , reactivity (psychology) , reagent , chemistry , class (philosophy) , organic chemistry , iodine compounds , combinatorial chemistry , computer science , medicine , alternative medicine , pathology , artificial intelligence
Amides of 2‐iodoxybenzoic acid (IBX amides, 1 ) are a new class of pentavalent iodine compounds with a pseudo‐benziodoxole structure. These 2‐iodoxybenzamides are useful reagents for the oxidation of alcohols, with a reactivity pattern similar to IBX (R=CH(CH 3 )CO 2 CH 3 or CH(CH 2 Ph)CO 2 CH 3 (in crystal structure shown)).