IBX Amides: A New Family of Hypervalent Iodine Reagents | Zendy

Zhdankin Viktor V. | Zendy; Koposov Alexey Y. | Zendy; Netzel Brian C. | Zendy; Yashin Nikolai V. | Zendy; Rempel Brian P. | Zendy; Ferguson Michael J. | Zendy; Tykwinski Rik R. | Zendy

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IBX Amides: A New Family of Hypervalent Iodine Reagents

Author(s) -

Zhdankin Viktor V.,

Koposov Alexey Y.,

Netzel Brian C.,

Yashin Nikolai V.,

Rempel Brian P.,

Ferguson Michael J.,

Tykwinski Rik R.

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200351018

Subject(s) - hypervalent molecule , iodine , reactivity (psychology) , reagent , chemistry , class (philosophy) , organic chemistry , iodine compounds , combinatorial chemistry , computer science , medicine , alternative medicine , pathology , artificial intelligence

Amides of 2‐iodoxybenzoic acid (IBX amides, 1 ) are a new class of pentavalent iodine compounds with a pseudo‐benziodoxole structure. These 2‐iodoxybenzamides are useful reagents for the oxidation of alcohols, with a reactivity pattern similar to IBX (R=CH(CH 3 )CO 2 CH 3 or CH(CH 2 Ph)CO 2 CH 3 (in crystal structure shown)).

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