Facile Formation of  N ‐Confused Porphyrin Dimers by Platinum( II ) Coordination to the Outer‐Nitrogen Atoms | Zendy

Furuta Hiroyuki | Zendy; Youfu Katsuyuki | Zendy; Maeda Hiromitsu | Zendy; Osuka Atsuhiro | Zendy

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Facile Formation of N ‐Confused Porphyrin Dimers by Platinum( II ) Coordination to the Outer‐Nitrogen Atoms

Author(s) -

Furuta Hiroyuki,

Youfu Katsuyuki,

Maeda Hiromitsu,

Osuka Atsuhiro

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200350995

Subject(s) - porphyrin , metallacycle , platinum , dimer , confusion , chemistry , atom (system on chip) , crystallography , aryl , stereochemistry , nitrogen , x ray crystallography , physics , photochemistry , computer science , organic chemistry , catalysis , psychology , alkyl , diffraction , psychoanalysis , optics , embedded system

Confusion but no doubt: Two types of Pt II dimer complexes of N ‐confused porphyrin (depicted) were synthesized and the structures were unequivocally elucidated by X‐ray crystal analyses. Both complexes contain a metallocycle that binds to a Pt center by an outer‐nitrogen atom of the confused porphyrin, and by an ortho ‐carbon atom of a meso ‐aryl group.

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