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Facile Formation of N ‐Confused Porphyrin Dimers by Platinum( II ) Coordination to the Outer‐Nitrogen Atoms
Author(s) -
Furuta Hiroyuki,
Youfu Katsuyuki,
Maeda Hiromitsu,
Osuka Atsuhiro
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200350995
Subject(s) - porphyrin , metallacycle , platinum , dimer , confusion , chemistry , atom (system on chip) , crystallography , aryl , stereochemistry , nitrogen , x ray crystallography , physics , photochemistry , computer science , organic chemistry , catalysis , psychology , alkyl , diffraction , psychoanalysis , optics , embedded system
Confusion but no doubt: Two types of Pt II dimer complexes of N ‐confused porphyrin (depicted) were synthesized and the structures were unequivocally elucidated by X‐ray crystal analyses. Both complexes contain a metallocycle that binds to a Pt center by an outer‐nitrogen atom of the confused porphyrin, and by an ortho ‐carbon atom of a meso ‐aryl group.