Convergent Paired Electrolysis for the Three‐Component Synthesis of Protected Homoallylic Alcohols | Zendy

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Convergent Paired Electrolysis for the Three‐Component Synthesis of Protected Homoallylic Alcohols

Author(s) -

Hilt Gerhard

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200350892

Subject(s) - electrolysis , electrophile , electrochemistry , nucleophile , holy grail , chemistry , product (mathematics) , coupling (piping) , component (thermodynamics) , inorganic chemistry , combinatorial chemistry , polymer chemistry , materials science , organic chemistry , electrode , computer science , metallurgy , mathematics , physics , catalysis , thermodynamics , world wide web , electrolyte , geometry

The holy grail of electrochemistry , a convergent paired electrolysis, is a step closer in the metal‐free electrochemical allylation of aromatic aldehydes in DMF. A three‐component coupling product is obtained in a one‐pot procedure when anodically generated electrophiles and cathodically generated nucleophiles react in solution to give a single product.

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