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Switching of a Spin‐Crossover‐Material Incorporated in Metal–Organic Frameworks by a Reversible Ligand‐Substitution Reaction in the Crystalline State
Author(s) -
Glaser Thorsten
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200301693
Subject(s) - spin crossover , ligand (biochemistry) , metal organic framework , spin states , desorption , molecule , spin transition , transition metal , materials science , crystal engineering , sorption , chemical physics , crossover , spin (aerodynamics) , chemistry , crystallography , inorganic chemistry , supramolecular chemistry , organic chemistry , thermodynamics , adsorption , catalysis , physics , biochemistry , receptor , computer science , artificial intelligence
A reversible ligand‐substition reaction in the crystal provides a possibility to switch spin‐crossover materials (see picture). The merger of spin‐crossover with the nanoporosity of metal–organic frameworks allows a dramatic variation of the cooperative interactions between the spin transition centers by sorption/desorption of guest molecules.