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Bioinorganic Reaction Mechanisms: From High‐Valent Iron to Bioorganometallic Chemistry
Author(s) -
Slep Leonardo D.,
Neese Frank
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200301649
Subject(s) - bioinorganic chemistry , chemistry , crystallography , stereochemistry
Important aspects of the mechanisms of fundamental bioinorganic reactions have been revealed in recent studies, which have shed light on the structure and properties of high‐valent nonheme Fe centers (left structure) as well as on the biosynthetic formation of the FeCN bond in Ni–Fe hydrogenases (right).