[Pd 3 (InCp*) 4 (μ 2 ‐InCp*) 4 ]: Three Linearly Arranged Palladium Atoms Wrapped into a Fluxional Shell of Eight InCp* Ligands | Zendy

Steinke Tobias | Zendy; Gemel Christian | Zendy; Winter Manuela | Zendy; Fischer Roland A. | Zendy

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[Pd 3 (InCp*) 4 (μ 2 ‐InCp*) 4 ]: Three Linearly Arranged Palladium Atoms Wrapped into a Fluxional Shell of Eight InCp* Ligands

Author(s) -

Steinke Tobias,

Gemel Christian,

Winter Manuela,

Fischer Roland A.

Publication year - 2002

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200290041

Subject(s) - tetramethylethylenediamine , organometallic chemistry , palladium , analogy , cluster (spacecraft) , chemistry , group 2 organometallic chemistry , crystallography , shell (structure) , stereochemistry , molecule , materials science , computer science , medicinal chemistry , catalysis , crystal structure , organic chemistry , epistemology , philosophy , programming language , composite material

There is still much to discover : The assumption that monovalent Group 13 organometallic compounds exhibit a high potential as ligands in organometallic chemistry beyond their analogy to CO is confirmed by the synthesis of the title compound 1 . Complex 1 , the structure of which is unique and has no analogue in carbonyl cluster chemistry, is prepared by reaction of [(tmeda)Pd(CH 3 ) 2 ] with [InCp*]. tmeda= N , N , N ′, N ′‐tetramethylethylenediamine, Cp*=pentamethylcyclopentadienide.

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