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New Ferrocenyl Ligands with Broad Applications in Asymmetric Catalysis
Author(s) -
Lotz Matthias,
Polborn Kurt,
Knochel Paul
Publication year - 2002
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200290024
Subject(s) - reactivity (psychology) , combinatorial chemistry , chemistry , enantioselective synthesis , ferrocene , catalysis , stereochemistry , organic chemistry , electrode , medicine , alternative medicine , pathology , electrochemistry
A new synthetic approach allows the synthesis of taniaphos‐analogous ligands 2 with inverted α configuration ( S p ,α S ). This new class of ferrocenyl ligands displays excellent enantioselectivity and enhanced reactivity in several types of asymmetric hydrogenation reactions (e.g. 1 → 3 ).
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