Novel Synthetic Approach to Trinuclear 3d‐4f Complexes: Specific Exchange of the Central Metal of a Trinuclear Zinc( II ) Complex of a Tetraoxime Ligand with a Lanthanide( III ) Ion | Zendy

Akine Shigehisa | Zendy; Taniguchi Takanori | Zendy; Nabeshima Tatsuya | Zendy

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Novel Synthetic Approach to Trinuclear 3d‐4f Complexes: Specific Exchange of the Central Metal of a Trinuclear Zinc( II ) Complex of a Tetraoxime Ligand with a Lanthanide( III ) Ion

Author(s) -

Akine Shigehisa,

Taniguchi Takanori,

Nabeshima Tatsuya

Publication year - 2002

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200290011

Subject(s) - transmetalation , lanthanide , chemistry , ligand (biochemistry) , zinc , metal , stereochemistry , combinatorial chemistry , crystallography , ion , receptor , biochemistry , organic chemistry , catalysis

Only the central metal atom of the homotrinuclear complex [LZn 3 ] 2+ , prepared by cooperative complexation between a linear ligand and Zn(OAc) 2 , is replaced with a Ln 3+ ion by selective and quantitative transmetalation to give a helical heterotrinuclear complex [LZn 2 Ln] 3+ (see scheme). Ln=lanthanide.

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