Synthesis, Characterization, and Reaction of Ethynyl(phenyl)‐λ 3 ‐Iodane Complex with [18]Crown‐6 | Zendy

Ochiai Masahito | Zendy; Miyamoto Kazunori | Zendy; Suefuji Takashi | Zendy; Sakamoto Shigeru | Zendy; Yamaguchi Kentaro | Zendy; Shiro Motoo | Zendy

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Synthesis, Characterization, and Reaction of Ethynyl(phenyl)‐λ 3 ‐Iodane Complex with [18]Crown‐6

Author(s) -

Ochiai Masahito,

Miyamoto Kazunori,

Suefuji Takashi,

Sakamoto Shigeru,

Yamaguchi Kentaro,

Shiro Motoo

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200250866

Subject(s) - 18 crown 6 , chemistry , iodine , crown (dentistry) , characterization (materials science) , methanol , evaporation , solid state , medicinal chemistry , inorganic chemistry , polymer chemistry , organic chemistry , materials science , nanotechnology , molecule , thermodynamics , physics , composite material

Iodine( III ) crowned : Slow evaporation of solvents afforded the 1:1 complex 1 between [HCCIPh]BF 4 and [18]crown‐6 (18C6). Both the solid‐state and solution structures of 1 were determined. Reaction of 1 with methanol proceeds in a Michael‐type fashion. The complexation with 18C6 increases the stability of labile λ 3 ‐iodanes, such as 1 .

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