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Enhancing the Enantioselectivity of Novel Homogeneous Organometallic Hydrogenation Catalysts
Author(s) -
Jones Matthew D.,
Raja Robert,
Thomas John Meurig,
Johnson Brian F. G.,
Lewis Dewi W.,
Rouzaud Jacques,
Harris Kenneth D. M.
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200250861
Subject(s) - homogeneous , catalysis , group 2 organometallic chemistry , chemistry , homogeneous catalysis , organometallic chemistry , organic chemistry , combinatorial chemistry , noyori asymmetric hydrogenation , enantioselective synthesis , molecule , physics , thermodynamics
By designing well‐defined , single‐site asymmetric organometallic complexes anchored to a concave siliceous support (see picture) high ee values may be obtained in heterogeneous catalytic hydrogenations. O red, Si orange, Rh yellow, C grey, N blue, F green, B pink, H white.