Template Synthesis of Polypyrrole Nanofibers Insulated within One‐Dimensional Silicate Channels: Hexagonal versus Lamellar for Recombination of Polarons into Bipolarons | Zendy

Ikegame Midori | Zendy; Tajima Keisuke | Zendy; Aida Takuzo | Zendy

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Template Synthesis of Polypyrrole Nanofibers Insulated within One‐Dimensional Silicate Channels: Hexagonal versus Lamellar for Recombination of Polarons into Bipolarons

Author(s) -

Ikegame Midori,

Tajima Keisuke,

Aida Takuzo

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200250800

Subject(s) - polypyrrole , materials science , lamellar structure , nanocomposite , polymerization , silicate , chemical engineering , schematic , composite material , polymer , electronic engineering , engineering

Very different electronic properties are found in the hexagonal and lamellar nanocomposite films (see schematic representations) prepared by dilution of a pyrrole‐containing surfactant with nonpolymerizable surfactants in a sol–gel‐based template polymerization. The hexagonal composite film comprises a thin polypyrrole nanocable covered with an insulating silicate channel.

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