All‐Hydrocarbon Inclusion Complexes of Carbon Nanorings: Cyclic [6]‐ and [8]Paraphenyleneacetylenes | Zendy

Kawase Takeshi | Zendy; Seirai Yohko | Zendy; Darabi Hossein R. | Zendy; Oda Masaji | Zendy; Sarakai Yasuyuki | Zendy; Tashiro Kohji | Zendy

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All‐Hydrocarbon Inclusion Complexes of Carbon Nanorings: Cyclic [6]‐ and [8]Paraphenyleneacetylenes

Author(s) -

Kawase Takeshi,

Seirai Yohko,

Darabi Hossein R.,

Oda Masaji,

Sarakai Yasuyuki,

Tashiro Kohji

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200250727

Subject(s) - hexamethylbenzene , conjugated system , toluene , hydrocarbon , molecule , inclusion (mineral) , carbon fibers , chemistry , chemical engineering , materials science , chemical physics , nanotechnology , organic chemistry , mineralogy , benzene , composite material , composite number , polymer , engineering

Ringing the changes : The belt‐shaped π‐conjugated [6]‐ and [8]paraphenyleneacetylenes exhibit nanosized cavities (see picture), and act as host molecules in crystalline inclusion complexes with hexamethylbenzene and toluene, respectively. The concave side of the cavities appears to possess a negative electronic potential.

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