Sodium Oligophosphanediide Ions in the PhPCl 2 /Na System: Syntheses and Structural Characterization | Zendy

Geier Jens | Zendy; Rüegger Heinz | Zendy; Wörle Michael | Zendy; Grützmacher Hansjörg | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Sodium Oligophosphanediide Ions in the PhPCl 2 /Na System: Syntheses and Structural Characterization

Author(s) -

Geier Jens,

Rüegger Heinz,

Wörle Michael,

Grützmacher Hansjörg

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200250725

Subject(s) - characterization (materials science) , ion , sodium , chemistry , materials science , nanotechnology , organic chemistry

A new look into an old pot : A new cluster structure is found for the cage anion 1 (see picture, L=dme) in the salt [Na(dme 3 )] + [Na 5 (P 2 Ph 2 )(dme) 3 ] − . This (structurally characterized) ionic compound is obtained in excellent yield when PhPCl 2 is simply reduced with sodium in a toluene/tetramethylethylene mixture. This method delivers catena ‐oligophosphane‐α,ω‐diides with two, three, or four phosphorus atoms.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research