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Conductive Organic Plastic Crystals Based on Pyrazolium Imides
Author(s) -
AbuLebdeh Yaser,
Alarco PierreJean,
Armand Michel
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200250706
Subject(s) - plastic crystal , materials science , lithium (medication) , solid state , electrical conductor , conductivity , phase (matter) , salt (chemistry) , doping , chemical engineering , composite material , optoelectronics , chemistry , organic chemistry , medicine , endocrinology , engineering
Plastic batteries : Pyrazolium trifluoromethanesulfonimide 1 displays a single plastic crystalline phase (20–65 °C). When doped with a lithium salt (2 mol %), solid‐state conductivity values above 10 −4 S cm −1 at 55 °C are measured. The superior properties of these materials make them candidates for a new generation of lithium batteries.