Premium
The Total Synthesis of Racemic Teucvin and 12‐ epi ‐Teucvin
Author(s) -
Liu HsingJang,
Zhu JiaLiang,
Chen IChia,
Jankowska Renata,
Han Yongxin,
Shia KakShan
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200250681
Subject(s) - regioselectivity , total synthesis , stereochemistry , chemistry , organic chemistry , catalysis
Complete face‐, stereo‐, and regioselectivity in the Diels–Alder reaction of compounds 1 and 2 was the key to the first total synthesis, in racemic form, of the 19‐norclerodane diterpenoids teucvin and 12‐ epi ‐teucvin.