Premium
Cocrystallization with Acetylene: Molecular Complexes with Acetone and Dimethyl Sulfoxide
Author(s) -
Boese Roland,
Kirchner Michael T.,
Billups W. Edward,
Norman Lewis R.
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200250634
Subject(s) - acetylene , acetone , dimethyl sulfoxide , chemistry , crystal structure , photochemistry , organic chemistry , materials science
Different phases : Molecular complexes of acetylene and acetone or DMSO are formed simultaneously in different phases. Crystalline acetylene:actone 1:2 (A) and 1:1 (B), as well as acetylene:DMSO 2:1 (C) complexes have been obtained by in situ cocrystallization under pressure in a capillary with the use of an IR laser. The crystal structures may be interpreted as a “frozen” situation of the liquids.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom