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Detection of Paramagnetic pH‐Dependent Inclusion Complexes between β‐Cyclodextrin Dimers and Nitroxide Radicals
Author(s) -
Franchi Paola,
Lucarini Marco,
Pedulli Gian Franco
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200250526
Subject(s) - nitroxide mediated radical polymerization , cyclodextrin , radical , chemistry , paramagnetism , inclusion (mineral) , component (thermodynamics) , photochemistry , polymer chemistry , organic chemistry , radical polymerization , polymerization , polymer , physics , mineralogy , quantum mechanics , thermodynamics
Three's company : The construction of a three‐component organic free radical has been obtained with symmetric nitroxides and β‐cyclodextrin. Its formation can be reversibly controlled by changing pH or temperature (see scheme).