Detection of Paramagnetic pH‐Dependent Inclusion Complexes between β‐Cyclodextrin Dimers and Nitroxide Radicals | Zendy

Franchi Paola | Zendy; Lucarini Marco | Zendy; Pedulli Gian Franco | Zendy

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Detection of Paramagnetic pH‐Dependent Inclusion Complexes between β‐Cyclodextrin Dimers and Nitroxide Radicals

Author(s) -

Franchi Paola,

Lucarini Marco,

Pedulli Gian Franco

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200250526

Subject(s) - nitroxide mediated radical polymerization , cyclodextrin , radical , chemistry , paramagnetism , inclusion (mineral) , component (thermodynamics) , photochemistry , polymer chemistry , organic chemistry , radical polymerization , polymerization , polymer , physics , mineralogy , quantum mechanics , thermodynamics

Three's company : The construction of a three‐component organic free radical has been obtained with symmetric nitroxides and β‐cyclodextrin. Its formation can be reversibly controlled by changing pH or temperature (see scheme).

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