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Synthesis of 2,3,6‐Trideoxysugar‐Containing Disaccharides by Cyclization and Glycosidation through the Sequential Activation of Sulfoxide and Methylsulfanyl Groups in a One‐Pot Procedure
Author(s) -
Amaya Toru,
Takahashi Daisuke,
Tanaka Hiroshi,
Takahashi Takashi
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200250218
Subject(s) - sulfoxide , chemistry , acceptor , glycosyl , dimethyl sulfoxide , group (periodic table) , glycosylation , organic chemistry , combinatorial chemistry , stereochemistry , biochemistry , condensed matter physics , physics
A one‐pot procedure for the synthesis of 2,3,6‐trideoxyglycosides 1 has been developed, based on the sequential activation of a sulfoxide group and a methylsulfanyl group in 2 , cyclization, and subsequent glycosidation with a glycosyl acceptor 3 .