Synthesis of 2,3,6‐Trideoxysugar‐Containing Disaccharides by Cyclization and Glycosidation through the Sequential Activation of Sulfoxide and Methylsulfanyl Groups in a One‐Pot Procedure | Zendy

Amaya Toru | Zendy; Takahashi Daisuke | Zendy; Tanaka Hiroshi | Zendy; Takahashi Takashi | Zendy

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Synthesis of 2,3,6‐Trideoxysugar‐Containing Disaccharides by Cyclization and Glycosidation through the Sequential Activation of Sulfoxide and Methylsulfanyl Groups in a One‐Pot Procedure

Author(s) -

Amaya Toru,

Takahashi Daisuke,

Tanaka Hiroshi,

Takahashi Takashi

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200250218

Subject(s) - sulfoxide , chemistry , acceptor , glycosyl , dimethyl sulfoxide , group (periodic table) , glycosylation , organic chemistry , combinatorial chemistry , stereochemistry , biochemistry , condensed matter physics , physics

A one‐pot procedure for the synthesis of 2,3,6‐trideoxyglycosides 1 has been developed, based on the sequential activation of a sulfoxide group and a methylsulfanyl group in 2 , cyclization, and subsequent glycosidation with a glycosyl acceptor 3 .

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