Proton‐Induced Change of the Coordination Mode of a Boron Group: Boryl Complexes [Mn(CO) 4 (PR 3 )(BH 2 ⋅PMe 3 )] and Cationic Borane σ Complexes [Mn(CO) 4 (PR 3 )(η 1 ‐BH 3 ⋅PMe 3 )] + | Zendy

Yasue Takahiro | Zendy; Kawano Yasuro | Zendy; Shimoi Mamoru | Zendy

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Proton‐Induced Change of the Coordination Mode of a Boron Group: Boryl Complexes [Mn(CO) 4 (PR 3 )(BH 2 ⋅PMe 3 )] and Cationic Borane σ Complexes [Mn(CO) 4 (PR 3 )(η 1 ‐BH 3 ⋅PMe 3 )] +

Author(s) -

Yasue Takahiro,

Kawano Yasuro,

Shimoi Mamoru

Publication year - 2003

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200219992

Subject(s) - heterolysis , protonation , cationic polymerization , borane , chemistry , boron , proton , crystallography , metal , decomposition , inorganic chemistry , photochemistry , ion , polymer chemistry , catalysis , organic chemistry , physics , quantum mechanics

Mode change on protonation : New borylmanganese complexes 1 undergo protonation to give cationic borane σ complexes 2 . Heterolytic cleavage of the metal‐coordinated BH bond was observed in the decomposition process of 2 .

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