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Proton‐Induced Change of the Coordination Mode of a Boron Group: Boryl Complexes [Mn(CO) 4 (PR 3 )(BH 2 ⋅PMe 3 )] and Cationic Borane σ Complexes [Mn(CO) 4 (PR 3 )(η 1 ‐BH 3 ⋅PMe 3 )] +
Author(s) -
Yasue Takahiro,
Kawano Yasuro,
Shimoi Mamoru
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200219992
Subject(s) - heterolysis , protonation , cationic polymerization , borane , chemistry , boron , proton , crystallography , metal , decomposition , inorganic chemistry , photochemistry , ion , polymer chemistry , catalysis , organic chemistry , physics , quantum mechanics
Mode change on protonation : New borylmanganese complexes 1 undergo protonation to give cationic borane σ complexes 2 . Heterolytic cleavage of the metal‐coordinated BH bond was observed in the decomposition process of 2 .