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A Pseudotetrahedral, High‐Oxidation‐State Organonickel Compound: Synthesis and Structure of Bromotris(1‐norbornyl)nickel( IV )
Author(s) -
Dimitrov Vladimir,
Linden Anthony
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200219383
Subject(s) - chemistry , nickel , 2 norbornyl cation , oxidation state , organometallic chemistry , catalysis , stereochemistry , polymer chemistry , medicinal chemistry , organic chemistry
A breath of fresh air : Air oxidation of [ n Bu 4 N] 2 [Ni II (1‐nor) 3 Br], prepared from [ n Bu 4 N] 2 [Ni II Br 4 ] and 1‐norbornyllithium generates the title pseudotetrahedral organometallic complex in which a nickel center with the formal oxidation state of +4 is present (see structure; Ni purple, Br brown, C black, H green).
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