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Reactions between Organomagnesium Reagents and Nitroarenes: Past, Present, and Future
Author(s) -
Ricci Alfredo,
Fochi Mariafrancesca
Publication year - 2003
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200201618
Subject(s) - reagent , combinatorial chemistry , functional group , chemistry , diversity (politics) , grignard reagent , biochemical engineering , organic chemistry , computer science , engineering , sociology , polymer , anthropology
Grignard reagents display useful diversity in their reactions with nitroarenes. Depending on the organomagnesium species used, these reactions, the results of which can be predicted from mechanistic studies, may lead to significantly diverse products (see scheme), and can be tailored towards the synthesis of substituted nitroarenes, indoles, and diarylamines. FG=functional group.