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Shape‐Selective Hydrogenation and Oxidation over a Platinum‐Containing Ultramicroporous Heteropolyoxometallic Compound
Author(s) -
Yoshinaga Yusuke,
Seki Kohei,
Nakato Teruyuki,
Okuhara Toshio
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199728331
Subject(s) - platinum , cyclohexene , molecule , chemistry , methane , materials science , inorganic chemistry , nuclear chemistry , photochemistry , organic chemistry , catalysis
Preferentially smaller molecules are oxidized and hydrogenated in the presence of the ultramicroporous (pore diameter < 5.9 Å), platinum‐containing (0.5 wt%) heteropolyoxometalate compound Pt/Cs 2.1 H 0.9 PW 12 O 40 , according to studies with methane/2,2‐dimethylpropane and ethene/cyclohexene (shown schematically on the right).