Stepwise Reaction of Bis(iodozincio)methane with Two Different Electrophiles | Zendy

Utimoto Kiitiro | Zendy; Toda Narihiro | Zendy; Mizuno Takeshi | Zendy; Kobata Masami | Zendy; Matsubara Seijiro | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Stepwise Reaction of Bis(iodozincio)methane with Two Different Electrophiles

Author(s) -

Utimoto Kiitiro,

Toda Narihiro,

Mizuno Takeshi,

Kobata Masami,

Matsubara Seijiro

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199728041

Subject(s) - electrophile , methane , stepwise reaction , chemistry , environmental science , organic chemistry , physics , order of reaction , catalysis , quantum mechanics , reaction rate constant , kinetics

[Pd 2 (dba) 3 ] in the presence of trifurylphosphane catalyzes the stepwise reaction of CH 2 (ZnI) 2 with different electrophiles [Eq. (a)]. The homologous Zn 2 compound CH 3 CH(ZnI) 2 reacts in the first step analogously with cinnamyl chloride; however, stoichiometric amounts of CuCN/LiCN are required for the coupling with allyl bromide in the second step

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research