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Structural Evolution from the Solid State to the Molecule for BaI 2 : Synthesis and Crystal Structures of [BaI 2 (μ 2 ‐OH 2 ) 2 ] 3/∞ , [BaI 2 (μ 2 ‐OH 2 )(OC 3 H 6 )] 2/∞ , [BaI 2 (thf) 3 ] 1/∞ , and [BaI 2 (thf) 5 ] · THF
Author(s) -
Fromm Katharina M.
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199727991
Subject(s) - solid state , molecule , crystallography , barium , crystal structure , chemistry , materials science , stereochemistry , inorganic chemistry , organic chemistry
The use of different donor ligands as chemical scissors allows fragments to be “cut out” from the solid‐state structure of BaI 2 , which results in the barium compounds given in the title. According to X‐ray structural analyses these compounds exhibit different dimensionalities.