Premium
From D ‐Glucose to a New Chiral Cyclooctenone
Author(s) -
Werschkun Barbara,
Thiem Joachim
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199727931
Subject(s) - sigmatropic reaction , sequence (biology) , derivative (finance) , carbohydrate , chemistry , simple (philosophy) , stereochemistry , organic chemistry , biochemistry , philosophy , epistemology , financial economics , economics
Loss of the carbohydrate structure accompanies the sigmatropic rearrangement of the doubly unsaturated saccharide derivative 1 . In this way, a highly functionalized eight‐membered carbocycle ( 2 ) is obtained in a simple reaction sequence from D ‐glucose.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom