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Carbohydrates Coordinated to Platinum( IV ) through Hydroxyl Groups: A New Class of Platinum Complexes with Bioactive Ligands
Author(s) -
Steinborn Dirk,
Junicke Henrik,
Bruhn Clemens
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199726861
Subject(s) - platinum , chemistry , platinum group , carbohydrate , stereochemistry , medicinal chemistry , combinatorial chemistry , organic chemistry , catalysis
In the first carbohydrate complexes of platinum( II ) . 1,2‐ O ‐isopropylidene‐α‐ D ‐gluco‐ and ‐α‐ D ‐allofuranose are coordinated to the trimethylplatinum cation only by three OH groups. These are also the only complexes of platinum that contain neutral carbohydrate ligands without anchor groups. The structure of the glucofuranose complex cation [PtMe 3 (C 9 H 16 O 6 )] − is depicted on the right.