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The Organic Chemsitry of Coordination Compounds: Unprecedented Substitution Reactions of Functionalized Polypyridine Complexes
Author(s) -
Tzalis Dimitrios,
Tor Yitzhak
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199726661
Subject(s) - substitution (logic) , substitution reaction , chemistry , coordination complex , combinatorial chemistry , organic chemistry , computer science , metal , programming language
The increased electrophilicity of the complexed phenanthroline ring and the resonance stabilization of the “anionic” addition intermediate account for the unprecedented reactivity of the Ru II and OS II coordination compounds shown in reaction (1), bpy = 2,2′‐bipyridine: M = Ru, Os; X = SCH 3 , OCH 3 , F.