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Solvation and the Synthesis of Self‐Assembled Capsules
Author(s) -
Tokunaga Yuji,
Rudkevich Dmitry M.,
Rebek Julius
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199726561
Subject(s) - covalent bond , solvation , solvent , molecule , chemistry , combinatorial chemistry , nanotechnology , materials science , organic chemistry
The solvent is the template! Reaction intermediates recognize solvent molecules S and encapsulate them (shown schematically on the right). The formation of covalent bonds could often proceed via noncovalently preassembled building blocks.