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Di‐, Tri‐, and Tetranuclear Alkoxyaluminum Hydrides
Author(s) -
Nöth Heinrich,
Schlegel Andreas,
Knizek Jörg,
Schwenk Holger
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199726401
Subject(s) - hydride , chemistry , crystallography , crystal structure , ion , aluminum hydride , stereochemistry , metal , organic chemistry , methoxide
O‐ and/or H‐bridged aluminum centers are found in the multinuclear alanes presented here. A peculiarity is the cage compound 1 (crystal structure shown on the right), in which all Al atoms are pentacoordinated. This is the first molecular compound with a tetracoordinated hydride ion.
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