Submolecularly Resolved Polymerization of Diacetylene Molecules on the Graphite Surface Observed with Scanning Tunneling Microscopy | Zendy

Grim Petrus C. M. | Zendy; De Feyter Steven | Zendy; Gesquière André | Zendy; Vanoppen Peter | Zendy; Rüker Markus | Zendy; Valiyaveettil Suresh | Zendy; Moessner Georg | Zendy; Müllen Klaus | Zendy; De Schryver Frans C. | Zendy

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Submolecularly Resolved Polymerization of Diacetylene Molecules on the Graphite Surface Observed with Scanning Tunneling Microscopy

Author(s) -

Grim Petrus C. M.,

De Feyter Steven,

Gesquière André,

Vanoppen Peter,

Rüker Markus,

Valiyaveettil Suresh,

Moessner Georg,

Müllen Klaus,

De Schryver Frans C.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199726011

Subject(s) - diacetylene , monolayer , scanning tunneling microscope , polymerization , photopolymer , materials science , graphite , isophthalic acid , molecule , photochemistry , polymer chemistry , crystallography , chemistry , nanotechnology , organic chemistry , composite material , polymer , polyester , terephthalic acid

The photopolymerization of a monolayer physisorbed on graphite and containing diacetylene derivatives comprising a isophthalic acid head group and a decyl group as nonpolar tail was studied by scanning tunneling microscopy (STM). The submolecularly resolved STM image on the right depicts a domain boundary between an unpolymerized monolayer (lower domain) and a polymerized monolayer (upper domain).

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