Tetrathia‐ and Tetraoxarubyrins: Aromatic, Core‐Modified, Expanded Porphyrins | Zendy

Srinivasan Alagar | Zendy; Reddy VenkatRam M. | Zendy; Narayanan S. Jeyaprakash | Zendy; Sridevi Bashyam | Zendy; Pushpan Simi K. | Zendy; Ravikumar Murugaeson | Zendy; Chandrashekar Tavarekere K. | Zendy

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Tetrathia‐ and Tetraoxarubyrins: Aromatic, Core‐Modified, Expanded Porphyrins

Author(s) -

Srinivasan Alagar,

Reddy VenkatRam M.,

Narayanan S. Jeyaprakash,

Sridevi Bashyam,

Pushpan Simi K.,

Ravikumar Murugaeson,

Chandrashekar Tavarekere K.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199725981

Subject(s) - protonation , chemistry , electrochemistry , aromaticity , proton nmr , combinatorial chemistry , adenosine , medicinal chemistry , stereochemistry , molecule , organic chemistry , electrode , ion , biochemistry

The remarkably simple synthesis of tetrathia‐ and tetraoxarubyrins 1 and 2 is achieved by the routes presented here. Spectroscopic, 1 H NMR, and electrochemical data suggest that 1, 2 , and their protonated derivatives are aromatic 26 π electron systems, and the protonated derivatives form stable complexes in solution with anions such as F − , N 3 − , and adenosine 5′‐monophosphate.

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