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Ligand‐Mediated Coupling of Organometallic Reaction Centers
Author(s) -
Kaim Wolfgang,
Reinhardt Ralf,
Fiedler Jan
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199724931
Subject(s) - redox , ligand (biochemistry) , chemistry , electron transfer , denticity , dissociation (chemistry) , chemical reaction , coupling reaction , photochemistry , combinatorial chemistry , inorganic chemistry , catalysis , crystallography , organic chemistry , receptor , biochemistry , crystal structure
Electron‐reservoir behavior , the formation of Rh I /Rh II mixed‐valent species, and the separation of redox processes and thus “communication” between individual reaction centers were established in a first systematic study of the ligand‐mediated coupling of two equivalent “chemical” redox (ECE) reaction centers (E = electron transfer, C = chemical step (here dissociation of chloride); see scheme on the right, Cp * = C 5 Me 5 , L = multidentate ligand).