Stabilization of a  C  2v ‐Distorted Methane Derivative in an Organometallic Framework | Zendy

Schottek Jörg | Zendy; Erker Gerhard | Zendy; Fröhlich Roland | Zendy

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Stabilization of a C 2v ‐Distorted Methane Derivative in an Organometallic Framework

Author(s) -

Schottek Jörg,

Erker Gerhard,

Fröhlich Roland

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199724751

Subject(s) - intramolecular force , group 2 organometallic chemistry , chemistry , tetrahedral molecular geometry , organometallic chemistry , methane , tetrahedron , ion , crystallography , coordination geometry , nuclear magnetic resonance spectroscopy , derivative (finance) , spectroscopy , stereochemistry , physics , molecule , crystal structure , organic chemistry , quantum mechanics , financial economics , economics , hydrogen bond

An intramolecular ion‐pair interaction stabilizes the unusual, distorted coordination geometry of C 1 in 1 . In the course of the topomerization 1 ⇋ ent ‐ 1 , which was followed by NMR spectroscopy, the internal Zr ⃛CH 2 ion pair must be cleaved. The rearrangement pathway probably proceeds via a species with “normal” tetrahedral coordination geometry at C 1 .

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