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Boryl Metal Complexes, Boron Complexes, and Catalytic (Hydro)boration
Author(s) -
Wadepohl Hubert
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199724411
Subject(s) - boron , borane , metal , catalysis , chemistry , transition metal , organic chemistry
Boryl metal complexes are not old hat , as demonstrated by the great interest in this class of compounds in recent years. Today, the importance of these complexes lies mainly in their role as intermediates in borylations catalyzed by transition metals [Eq. (1)], for which there are numerous synthetic applications. With regard to new types of structures, the combinations metal complex/borane continues to produce many novelties, for example σ complexes of type 1.