Selective Enhancement of NMR Signals for α‐Cyclodextrin with Laser‐Polarized Xenon | Zendy

Song YiQiao | Zendy; Goodson Boyd M. | Zendy; Taylor Rebecca E. | Zendy; Laws David D. | Zendy; Navon Gil | Zendy; Pines Alexander | Zendy

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Selective Enhancement of NMR Signals for α‐Cyclodextrin with Laser‐Polarized Xenon

Author(s) -

Song YiQiao,

Goodson Boyd M.,

Taylor Rebecca E.,

Laws David D.,

Navon Gil,

Pines Alexander

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199723681

Subject(s) - xenon , cyclodextrin , molecule , nuclear magnetic resonance , isotopes of xenon , laser , chemistry , materials science , atomic physics , physics , optics , organic chemistry

“Lighting up” the nuclear magnetic resonance of molecules with laser‐polarized xenon could be a valuable new source of structural information. The 1 H NMR signals of protons near the xenon binding site in α‐cyclodextrin (shown schematically on the right) are selectively enhanced through couplings that are sensitive to 129 Xe 1 H internuclear distances.

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