Fluorous Biphasic Catalysis: Complexation of 1,4,7‐[C 8 F 17 (CH 2 ) 3 ] 3 ‐1,4,7‐Triazacyclononane with [M(C 8 F 17 (CH 2 ) 2 CO 2 ) 2 ] (M = Mn, Co) To Provide Perfluoroheptane‐Soluble Catalysts for Alkane and Alkene Functionalization in the Presence of  t ‐BuOOH and O 2 | Zendy

Vincent JeanMarc | Zendy; Rabion Alain | Zendy; Yachandra Vittal K. | Zendy; Fish Richard H. | Zendy

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Fluorous Biphasic Catalysis: Complexation of 1,4,7‐[C 8 F 17 (CH 2 ) 3 ] 3 ‐1,4,7‐Triazacyclononane with [M(C 8 F 17 (CH 2 ) 2 CO 2 ) 2 ] (M = Mn, Co) To Provide Perfluoroheptane‐Soluble Catalysts for Alkane and Alkene Functionalization in the Presence of t ‐BuOOH and O 2

Author(s) -

Vincent JeanMarc,

Rabion Alain,

Yachandra Vittal K.,

Fish Richard H.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199723461

Subject(s) - autoxidation , catalysis , carboxylate , ligand (biochemistry) , chemistry , homogeneous catalysis , stereochemistry , medicinal chemistry , organic chemistry , biochemistry , receptor

An autoxidation mechanism was involved in the oxidation of alkanes and alkenes with t BuOOH and O 2 under conditions of fluorous biphasic catalysis. The catalytically active complexes are soluble in perfluoroheptane and form in situ from ligand 1 and the Mn 2+ complex 2 with polyfluorinated carboxylate ligands (fluoroponytails).

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