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Fluorous Biphasic Catalysis: Complexation of 1,4,7‐[C 8 F 17 (CH 2 ) 3 ] 3 ‐1,4,7‐Triazacyclononane with [M(C 8 F 17 (CH 2 ) 2 CO 2 ) 2 ] (M = Mn, Co) To Provide Perfluoroheptane‐Soluble Catalysts for Alkane and Alkene Functionalization in the Presence of t ‐BuOOH and O 2
Author(s) -
Vincent JeanMarc,
Rabion Alain,
Yachandra Vittal K.,
Fish Richard H.
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199723461
Subject(s) - autoxidation , catalysis , carboxylate , ligand (biochemistry) , chemistry , homogeneous catalysis , stereochemistry , medicinal chemistry , organic chemistry , biochemistry , receptor
An autoxidation mechanism was involved in the oxidation of alkanes and alkenes with t BuOOH and O 2 under conditions of fluorous biphasic catalysis. The catalytically active complexes are soluble in perfluoroheptane and form in situ from ligand 1 and the Mn 2+ complex 2 with polyfluorinated carboxylate ligands (fluoroponytails).