Incorporation of a First Row Element into the Bridge of a Strained Metallocenophane: Synthesis of a Boron‐Bridged [1]Ferrocenophane | Zendy

Braunschweig Holger | Zendy; Dirk Regain | Zendy; Müller Matthias | Zendy; Nguyen Paul | Zendy; Resendes Rui | Zendy; Gates Derek P. | Zendy; Manners Ian | Zendy

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Incorporation of a First Row Element into the Bridge of a Strained Metallocenophane: Synthesis of a Boron‐Bridged [1]Ferrocenophane

Author(s) -

Braunschweig Holger,

Dirk Regain,

Müller Matthias,

Nguyen Paul,

Resendes Rui,

Gates Derek P.,

Manners Ian

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199723381

Subject(s) - cyclopentadienyl complex , bridge (graph theory) , polymerization , boron , element (criminal law) , tilt (camera) , polymer chemistry , ring (chemistry) , polymer , crystallography , materials science , chemistry , composite material , structural engineering , organic chemistry , engineering , catalysis , medicine , political science , law

A new record tilt angle [32.4(2)°] is present between the planes of the cyclopentadienyl ligands in the [1]boraferrocenophane 1 . This compound is the first [1]ferrocenophane containing a first row element in the bridge. Ring‐opening polymerization of 1 leads to cyclic oligomers and insoluble polymer 2 .

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